2017-8-22 & 0183; The effects of different outer diameters and concentrations of multi-walled carbon nanotubes on polysulfone PS hollow fiber membranes were investigated. Nanocomposite solutions were formed by adding 0.01 0.05 0.2 and 0.5 wt% multi-walled-carbon nanotubes MWCNT having 20–30 8–15 and <8 nm outer diameters to PS. Subsequently fabri ed membranes were characterized
2019-3-6 & 0183; Bio alysis of large-sized substrates finds wide appli ions. Immobilizing the involved enzymes on solid supports improves bio alysis yet faces challenges such as enzyme structural perturbation leaching and low cost-efficiencies depending on immobilization strategies/matrices. Carbon nanotubes CNTs are attractive matrices but challenged by enzyme leaching physical adsorption or
2001-10-19 & 0183; The equilibrium partitioning of lipophilic ion-exchanger salts from ion-selective ic membrane electrodes ISEs and its possible effect on the lower detection limit of these sensors is described. Predictions are made on the basis of various parameters including the knowledge of tetraphenylborate potassium salt partitioning constants the selectivity of ionophore-free ion-exchanger
Ayomide H. Labulo Bice S. Martincigh Bernard Omondi and Vincent O. Nyamori Advances in carbon nanotubes as efficacious supports for palladium- alysed carbon–carbon cross-coupling reactions Journal of Materials Science 10.1007/s10853-017-1128-0 52 16 9225-9248 2017 .
2019-7-31 & 0183; As a bonus by including a small amount of manganese buried far from the surface of the nanotubes to prevent it from leaching into water the minute springs became magnetic.
2015-6-1 & 0183; Gold nanoparticles AuNPs with sizes between 3 and 10 nm were firmly supported on pristine multi-walled carbon nanotubes MWCNT in high yields by a facile linker-free deposition route using aqueous suspensions of pre-reduced gold precursors. For the first time the resulting AuNP-MWCNT hybrid material was employed as alyst for the hydrogenation of a series of substituted nitroarenes Cited by: 12
2006-7-19 & 0183; Ayomide H. Labulo Bice S. Martincigh Bernard Omondi Vincent O. Nyamori Advances in carbon nanotubes as efficacious supports for palladium- alysed carbon–carbon cross-coupling reactions Journal of Materials Science 10.1007/s10853-017-1128-0 52 16 9225-9248 2017 .
Recently single walled carbon nanotubes SWNTs —in the form of deposited aggregates and membrane coatings—have been shown to be highly toxic toward microbes. 27 Their chemical stability and ease of functionalization make SWNT attractive components toward antimicrobial biomaterials. However pure SWNT materials/coatings are costly and offer
2021-4-16 & 0183; Tang X. B. Gao and Z. X. Jin* “Pre-leaching strategy for constructing Co 2 P/Co P/N-doped carbon towards enhanced bifunctional oxygen electro alysis” Electrochimica Acta 2020 337
2021-7-27 & 0183; The leaching in a soil column test showed that the movement of carbon nanotubes was inhibited being confined mainly to the topmost layers of the soil. This is
The work described in this thesis is concerned with the development of fullerenes and single-walled carbon nanotubes SWNTs derivatives by novel chemistries for two main objectives: i use of fullerenes derivatives and single-walled carbon nanotubes SWNTs as a platform for drug delivery; ii use of functionalised SWNTs in nanoparticles alysts for low temperature fuel cells appli ions.
2014-1-1 & 0183; The U.S. Department of Energy's Office of Scientific and Technical Information
The Pd leaching and particle coalescence are the main reasons for the loss of activity. An extraordinary im- Palladium on carbon nanotubes; Gold–palladium alyst 1. Introduction Metal alyzed alcohol oxidation in the liquid phase using oxygen as the oxidant represents a well known inter-esting process but its industrial exploitation
Results and discussion check the complete AuCl4 reduction and the formation of Plasmon peak. Within few minutes of sol generation the gold 3.1. Catalytic activity of Pd supported on AC and CNTs sol was immobilised by adding carbon nanotubes acidified until pH 2 by sulphuric acid under vigorous stirring.
2021-2-1 & 0183; With such advantages activated carbon adsorption has been successfully applied in gold recovery from gold-thiourea and gold-iodide complex solutions Teirlinck and Petersen 1996 Zhang et al. 2004 . Currently advances in research on activated carbon have primarily focused on its modifi ion such as modifi ion of the surface structure properties chemical characterization and Cited by: 1
2017-4-28 & 0183; CNTs can be classified based on the number of graphene cylinders i.e. single-walled carbon nanotubes SWCNTs double-walled carbon nanotubes DWCNTs or multi-walled carbon nanotubes MWCNTs . SWCNTs have only one graphene cylinder of internal diameter in the range of 0.4–2.5 nm with a length in the micron to millimetre range.Cited by: 27
2013-6-13 & 0183; We have developed a biosensor for highly sensitive and selective determination of the endocrinic disruptor bisphenol A BPA . It is based on glassy carbon electrode modified with calf thymus DNA and a composited prepared from single walled carbon nanotubes SWNT and Nafion. The interaction between BPA and DNA was studied by voltammetry. The binding constant was determined
2016-7-29 & 0183; An electrochemiluminescence ECL sensor for bisphenol A was proposed by using l-cysteine-functionalized multiwalled carbon nanotubes/gold nanocomposites-modified glassy carbon electrode MWCNTs-Au/GCE based on ECL of peroxydisulfate solution. The ECL behaviors of peroxydisulfate solution had been investigated at the chitosan/MWCNTs-Au/GCE and bisphenol A
2019-5-26 & 0183; Controlled Functionalization of Multiwalled Carbon Nanotubes with Various Molecular-Weight Poly l-lactic acid . The Journal of Physical Chemistry B 2005 109 47 22237-22243.
2020-6-24 & 0183; molecules Article Increased Recovery of Gold Thiosulfate Alkaline Solutions by Adding Thiol Groups in the Porous Structure of Activated Carbon Freddy R. Escobar-Ledesma 1* Carlos F. Arag& 243;n-Tobar 1 Patricio J. Espinoza-Montero 2 and Ernesto de la Torre-Chauvin 1* 1 Department of Extractive Metallurgy Escuela Polit& 233;cnica Nacional Ladr& 243;n de Guevara E11-253
2014-9-1 & 0183; Ordered mesoporous carbon OMC nanoscaffolds are engineered agglomerates of carbon nanotubes held together by small carbon nanofibers with uniform pore sizes high pore volume and high channel permeability. These materials exhibit very high affinity for the adsorption of gold
Common nanoparticles used to improve conductivity in flexible sensors include gold and silver nanowires graphene carbon black and carbon nanotubes CNTs 1011 . These highly flexible nanocomposites have been used to produce a signal in response to mechanical input inducing a change in the measurable electrical properties of the material.
With respect to the elution step in cyanide medium gold loaded onto the nanotubes can be eluted with acidic thiourea solutions whereas in the chloride medium and due to that the adsorption process involved the precipitation of zero valent gold onto the multiwalled carbon nanotubes the elution has been considered as a leaching step with aqua regia. Francisco Jose Alguacil
2016-2-10 & 0183; Recently design strategies like encapsulating 3d transition metals into carbon nanotubes and graphene nanoshells have been reported to improve the
2013-8-27 & 0183; Steps: 1 synthesis of melamine formaldehyde MF with nickel nitrate and carbon particles; 2 pyrolysing metal-salt/MF- precursor; and 3 acid leaching of the pyrolysed samples.
2008-1-29 & 0183; High-density gold/platinum hybrid nanoparticles were lo ed on the surface of 1-D coaxial nanocables with high surface-to-volume ratios. It was found that this hybrid nanomaterial exhibits a high electro alytic activity for enhancing oxygen reduction low overpotential associated with the oxygen reduction reaction and almost four-electron electroreduction of dioxygen to water .Cited by: 180
2019-5-26 & 0183; In this article the in situ preparation of palladium nanoparticles as mediated by the self-regulated reduction of palladium acetate with the aid of sodium dodecyl sulfate SDS followed by subsequent deposition onto single-walled carbon nanotubes and multiwalled carbon nanotubes MWCNTs is reported. The surfactant SDS plays a dual role namely aids the solubilization of carbon nanotubes
Abstract. Gold 1 wt.% was loaded on several types of carbon materials activated carbon based carbon xerogels multi-walled carbon nanotubes nanodiamonds microdiamonds graphite and silicon carbide using two different methods sol immobilisation and double impregnation .
Carbon nanotubes are made from rolled up sheets of graphene and are classified as single-walled SWCNTs or multiwalled carbon nanotubes MWCNTs as shown in Figure 3 depending on the constituent numbers of graphene layers. Due to their unique size and shape much effort has been dedi ed to analyzing biomedical appli ions of CNTs.
2020-9-14 & 0183; Tang D. M. et al. Structural changes in Iron oxide and gold alysts during nucleation of carbon nanotubes studied by in situ transmission electron microscopy. ACS Nano 8 292–301 2014 .
2020-8-3 & 0183; 1 Dye diazonium-modified carbon nanotubes with immobilized gold nanoparticles as nanohybrid electro alyst of direct methanol oxidation Asma Bensgha& 239;er1* Viplove Bhullar2 1Navdeep Kaur2 Momath Lo3 Myriam Bdiri Aman Mahajan2* Mohamed M. Chehimi1* 1 Universit& 233; Paris Est ICMPE UMR7182 CNRS UPEC F-94320 Thiais France 2 Department of Physics Guru Nanak
The carbon nanostructures such as carbon nanotubes and graphene decorated with gold nanoparticles exhibit promising gas sensing appli ions with enhanced sensitivity. View Show abstract
2018-1-1 & 0183; Herein fluorine-doped carbon nanotubes F-CNTs were synthesized via a facile method and characterized by X-ray diffraction XRD X-ray photoelectron spectroscopy XPS and Raman spectroscopy. The as-synthesized F-CNTs exhibited notably enhanced alytic activity towards alytic ozonation for the degradation of organic pollutants.
As a result of the experiments although higher gold leaching extents were obtained in CIL process the increase in extent was about maximum 8% and the highest gold leaching extent was obtained as
Gold nanoparticles were deposited on carbon nanotubes to provide access to a nanohybrid structure which was involved in the aerobic oxidation of alcohols.
2017-4-28 & 0183; Since the 1970s palladium- alysed carbon–carbon C–C bond formation has made a critical impact in organic synthesis. In early studies homogeneous palladium alysts were extensively used for this reaction with limitations such as difficulty in separation and recycling ability. Lately heterogeneous palladium-based alysts have shown promise as surrogates for conventional
2008-1-29 & 0183; Point-Defect Mediated Bonding of Pt Clusters on 55 Carbon Nanotubes. The Journal of Physical Chemistry C 2009 113 3 890-893. DOI: 10.1021/jp810277b. Shaojun Guo Liang Wang Shaojun Dong and Erkang Wang . A Novel Urchinlike Gold/Platinum Hybrid
Pd nanoparticles supported on carbon nanotubes CNTs showed a higher selectivity than Pd nanoparticles supported on activated carbon AC in the liquid phase oxidation of benzylic alcohol to benzaldehyde. Under solventless conditions a significant improvement in selectivity was observed for Pd/CNTs whereas using Pd/AC a considerable over-oxidation of benzaldehyde was observed.
Gold nanoparticles supported on carbon nanotubes were shown to efficiently alyze the oxidation of alcohols to methyl esters under mild and selective reaction conditions. The reaction works with low alyst loadings and the nanohybrid could be readily recycled and reused.
2018-11-16 & 0183; With respect to the elution step in cyanide medium gold loaded onto the nanotubes can be eluted with acidic thiourea solutions whereas in the chloride medium and due to that the adsorption process involved the precipitation of zero valent gold onto the multiwalled carbon nanotubes the elution has been considered as a leaching step with aqua
Catalyst recycling was tested up to six consecutive cycles for the most active alytic system gold deposited on carbon nanotubes by sol immobilisation and it was found that the alyst maintains almost the original level of activity after several reaction cycles there was only a 6% drop in activity after the sixth cycle with a rather high selectivity to cyclohexanol and cyclohexanone and with no alyst leaching.Cited by: 88
Core electrode of a working electrode was obtained by depositing the paste of Gold nanoparticles and Multi-walled Carbon Nanotubes on a gold wire. The acetylcholinesterase enzyme was immobilized on carboxylated Single-walled Carbon Nanotubes and pasted onto a core of electrode followed by coating with a nafion layer to prevent enzyme leaching from the electrode.Cited by: 5
2016-1-1 & 0183; "Engineering Carbon Materials from the Hydrothermal Carbonization HTC Process of Biomass" Adv. Mater. 2009 in press Special Issue of New Carbon Materials . September 18 2009: Congratulations on the discovery of a new family of lamellar transition metal molybdate-CTA mesostructured composites Metal = Ni Co by Hongbin Yao Xiaobao Li et al which has been
2006-3-28 & 0183; Carbon nanotubes CNTs exhibit a unique combination of excellent mechanical electrical and electrochemical properties which has stimulated increasing interest in the appli ion of CNTs as components in bio sensors. This review highlights various design methodologies for CNT-based biosensors and their employment for the detection of a number of biomolecules.